烃源岩不同性质有机酸的分离及其检测方法     

杜佳宗  何蓓  蔡进功  雷天柱  刘庆  谢忠怀 《高校地质学报》2020,26(5):540-548

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。  相似文献   

Concurrent Determination of U‐Pb Age and REE Mass Fractions of Zircon by High Mass Resolution SIMS     

Yu Liu  Qiu‐Li Li  Guo‐Qiang Tang  Xian‐Hua Li 《Geostandards and Geoanalytical Research》2020,44(3):421-437

A combined geochronological and geochemical investigation for the same domain of zircon provides valuable information on timing and genesis, particularly in the case of multi‐growth metamorphic zircon. A high spatial resolution concurrent analytical method for zircon U‐Pb age and rare earth element content was successfully achieved in this study, using a multi‐collector secondary ion mass spectrometer (SIMS) at a ~ 8 μm diameter scale. Special instrument parameters were employed, including a high mass resolution of approximately 15000 applied to replace the previous energy filter method, and a dynamic multi‐collector mode used to reduce the measurement time to 18 min per analysis. Six zircon reference materials yielded precise and accurate ²⁰⁶Pb/²³⁸U ages, which are comparable to those obtained by the ordinary mono‐collector method, but with 2–3 times higher spatial resolution. All zircon grains measured in this study showed enriched heavy‐REE (HREE) contents consistent with previously reported values determined by LA and solution ICP‐MS methods. The light‐REE (LREE) mass fractions measured using both SIMS and LA‐ICP‐MS methods in this study, although with quite different volume, show consistent results within uncertainties.  相似文献   

Tectonic nature of the NE Asian continental margin during the Late Jurassic–Early Cretaceous: constraints from the geochronology and geochemistry of igneous rocks in the NE North China Craton     

Xiao-Ming Zhang  Chen-Yang Sun  Feng Wang  Yu Li 《International Geology Review》2020,62(15):1949-1970

ABSTRACT

This paper presents geochronological, geochemical, and zircon Hf–O isotope data for late Mesozoic intrusive rocks from the northeastern North China Craton (NCC), with the aim of constraining the late Mesozoic tectonic nature of the NE Asian continental margin. U–Pb zircon data indicate that the Late Mesozoic magmatism in the northeastern NCC can be subdivided into two stages: Late Jurassic (161 ? 156 Ma) and Early Cretaceous (125 ? 120 Ma). Late Jurassic magmatism consists mainly of monzogranites. These monzogranites display high Sr/Y ratios and the tetrad effect in their REE, respectively, and have negative ε_Hf(t) values (?22.6 to ?15.8). The former indicates that the primary magma was generated by partial melting of thickened NCC lower crust, the latter suggests that the monzogranites were crystallized from highly fractionated magma, with the primary magma derived from partial melting of lower continental crust. Combined with the spatial distribution and rock associations of the Late Jurassic granitoids, we conclude that the Late Jurassic magmatism in the eastern NCC formed in a compressional environment related to oblique subduction of the Paleo-Pacific Plate beneath the Eurasia. The Early Cretaceous magmatism consists mainly of granitoids and quartz diorites. The quartz diorites formed by mixing of melts derived from the mantle and lower crust. The coeval granitoids are classified as high-K calc-alkaline and metaluminous to weakly peraluminous series. Some of the granitoids are similar to A-type granites. The granitoid ε_Hf(t) values and T_DM2 range from ?14.3 to ?1.4 and 2089 to 1274 Ma, respectively. These values indicate that their primary magma was derived from partial melting of lower crustal material of the NCC, but with a contribution of mantle-derived material. We therefore conclude that Early Cretaceous magmatism in the northeastern NCC occurred in an extensional environment related to westward subduction of the Paleo-Pacific Plate beneath Eurasia.  相似文献   

华北南缘中元古界高山河群碎屑锆石U-Pb年代学及其地质意义^*          下载免费PDF全文

王淼  周洪瑞  张恒 《古地理学报》2020,22(1):39-55

为了探讨华北板块南缘中元古代沉积地层的时代归属和物质来源、区域古地理格局和大地构造特征,对豫西灵宝福地地区的高山河群进行碎屑锆石U-Pb年代学和锆石微量元素特征研究。获得的高山河群年龄最小(年轻)的单颗碎屑锆石 ²⁰⁷Pb/²⁰⁶Pb 年龄值为1685±39 Ma,从而限制了高山河群最早沉积年龄不早于1700 Ma。结合上覆的龙家园组年代学标定(1594±12 Ma),将高山河群的形成年代限定为1700—1600 Ma,即中元古代长城纪的中晚期,属国际地质年表的“固结纪”。高山河群中碎屑锆石 ²⁰⁷Pb/²⁰⁶Pb 年龄范围为1685—2751 Ma,呈现1850 Ma、2150 Ma、2300 Ma和2500 Ma共4个年龄峰值,对应于华北克拉通古元古代重要的地质事件,并且高山河群以1850 Ma和2500 Ma峰值年龄段的地质体为主要的物源区。根据高山河群与云梦山组碎屑锆石年龄频率对比,推测在豫西地区西侧存在以往报道较少的年龄为2500 Ma的地质体。根据熊耳群火山岩及其对应锆石的地球化学特征和熊耳期盆地动力学性质,并结合高山河群沉积相特征和沉积盆地构造属性,认为熊耳群形成于与“岛弧”共生的拉张性质的弧后盆地地区,而其上覆的高山河群为弧后盆地靠近大陆一侧的具有被动大陆边缘性质的滨浅海沉积。  相似文献   

川西甲基卡矿床外围中酸性侵入岩LA-ICP-MS锆石U-Pb年龄及地球化学特征     

李名则  秦宇龙  赵春  詹涵钰  周雄  孙光银 《中国地质调查》2020,7(5):1-9

在川西甲基卡矿床外围新发现了建巴村中酸性侵入岩体,为了探讨其形成时代、成岩构造背景及其成矿条件,开展了LA-ICP-MC锆石U-Pb年代学和地球化学特征研究。结果表明: 该岩体的结晶年龄为(211.8±1.0) Ma; 岩石属于钙碱性-高钾钙碱性准铝质中酸性侵入岩系列,具有I型花岗岩类的特征,其物质来源可能为壳源物质与幔源物质部分熔融。地球化学特征表明其形成于后碰撞环境,与此时期内川西地区的区域性岩浆活动相对应。建巴村岩体的构造位置及岩浆活动特征指示其可能不具备形成伟晶岩矿床的条件。  相似文献   

拟穴青蟹(Scylla paramamosain)六个地理群体肌肉氨基酸和脂肪酸的比较分析     

李永亮  赵欢欢  李荣华  王春琳  母昌考  宋微微  叶央芳 《海洋与湖沼》2019,50(2):465-472

本文对广西钦州(Gq)、福建霞浦(Fx)、浙江温州(Zw)、浙江三门(Zs)、浙江宁海(Zn)、浙江慈溪(Zc)等6个野生群体拟穴青蟹(Scylla paramamosain)肌肉进行了氨基酸及脂肪酸分析。共测定出19种游离氨基酸和26种脂肪酸。氨基酸含量在80.94—191.39mg/g之间, Gq为最高;总脂肪酸含量在7.97—11.38mg/g之间,Zn为最高。主要氨基酸为甘氨酸和精氨酸;主要脂肪酸为C20:5n3(EPA),占总脂肪酸含量的平均值为(22.47±5.84)%。各群体风味氨基酸和多不饱和脂肪酸含量丰富,占总氨基酸比例(TDAA/TFAA)和总脂肪酸比例(PUFA/TFA)分别为(53.62±5.43)%和(59.27±5.29)%。Zs群体的必需氨基酸含量及C22:6n3(DHA)均为最高。主成分分析结果表明:各群体的氨基酸与脂肪酸组成与含量相似性与地理距离分布具有一定的相关性,特别是Gq群体,在氨基酸与脂肪酸的分类中与其他群体区分比较明显。各群体风味氨基酸和多不饱和脂肪酸的聚类分析结果均表明:Zw、Zc与Gq群体较为接近,具有较强的甜味; Fx、Zn与Zs群体较为接近,具有较强的香味及不饱和脂肪酸营养价值。  相似文献   

玉米素和水杨酸对雨生红球藻(Haematococcus pluvialis)生长及虾青素积累的影响     

崔丹丹  杨柳  孙雪  邹昭敏  李亚鹤  张琳  徐年军 《海洋与湖沼》2018,49(3):682-691

虾青素是一种具有强抗氧化活性的类胡萝卜素,而雨生红球藻是天然虾青素的主要来源。本文以雨生红球藻(Haematococcus pluvialis)为材料,研究了植物激素玉米素和水杨酸对雨生红球藻的生长、虾青素含量及相关基因表达的影响。分别添加5种浓度的玉米素或水杨酸,结果发现0.05mg/L玉米素或25mg/L水杨酸处理5d后雨生红球藻虾青素积累最多。该浓度玉米素或水杨酸可显著提高光胁迫下藻细胞密度,最高分别达到3.4×10~5cell/mL和3.0×10~5cell/mL;同时玉米素与水杨酸组中虾青素含量显著上升,分别为1.7%和1.6%,比对照组分别增加29.2%和25.6%。玉米素缓解了高光逆境条件下光合作用基因——Rubisco大亚基(rbcL)及其活化酶(rca)、碳酸酐酶(ca)的下调表达,但对虾青素合成途径β-胡萝卜素酮化酶基因(bkt)的表达量没有显著影响;而水杨酸则相反,在胁迫后期不能缓解光合作用相关基因的下调表达,但可使bkt基因显著上调,最高可达对照组的2.5倍。本研究首次比较了玉米素和水杨酸对雨生红球藻生长和虾青素积累的影响,发现玉米素比水杨酸具有更好的促进雨生红球藻中虾青素积累的效果。  相似文献   

Geochemistry,detrital zircon geochronology and Hf isotope of the clastic rocks in southern Tibet: Implications for the Jurassic-Cretaceous tectonic evolution of the Lhasa terrane     

《Gondwana Research》2020

In order to reconstruct tectonic evolution history of the southern margin of Asia (i.e., Lhasa terrane) before the India-Asia collision, here we present a comprehensive study on the clastic rocks in the southern Lhasa terrane with new perspectives from sedimentary geochemistry, detrital zircon geochronology and Hf isotope. Clasts from the Jurassic-Early Cretaceous sedimentary sequences (i.e., Yeba and Chumulong Formations) display high compositional maturity and experienced moderate to high degree of chemical weathering, whereas those from the late Early-Late Cretaceous sequences (Ngamring and Shexing Formations) are characterized by low compositional maturity with insignificant chemical weathering. Our results lead to a coherent scenario for the evolution history of the Lhasa terrane. During the Early-Middle Jurassic (∼192-168Ma), the Lhasa terrane was speculated to be an isolated geological block. The Yeba Formation is best understood as being deposited in a back-arc basin induced by northward subduction of the Neo-Tethys ocean with sediments coming from the interiors of the Lhasa terrane. The Middle Jurassic-Early Cretaceous Lhasa-Qiangtang collision resulted in the formation of a composite foreland basin with southward-flowing rivers carrying clastic materials from the uplifted northern Lhasa and/or Qiangtang terranes. During the late Early-Late Cretaceous (∼104-72Ma), the Gangdese magmatic arc was uplifted rapidly above the sea level, forming turbidites (Ngamring Formation) in the Xigaze forearc basin and fluvial red beds (Shexing Formation) on the retro-arc side. At the end of Late Cretaceous, the Lhasa terrane was likely to have been uplifted to high elevation forming an Andean-type margin resembling the modern South America before the India-Asia collision.  相似文献   

化学刺激法提高花岗岩类岩石裂隙渗透性的实验研究     

郭清海  何曈  庄亚芹  骆进  张灿海 《地学前缘》2020,27(1):159-169

增强型地热系统(EGS)用于通过人工形成地热储层的方法从深部低渗透性岩体中开采地热能;国际上常采用水力压裂辅以化学刺激的方法改造EGS 储层以提高其渗透率。本文以采自青海共和盆地的花岗闪长岩样品为对象,选用3种不同化学刺激剂(氢氧化钠、盐酸和土酸),在3组不同注入流速条件下开展了系统化学刺激实验。结果表明:注入盐酸和土酸后样品渗透率均有提高,且采用土酸时渗透率提高幅度明显大于盐酸;但注入氢氧化钠后,样品渗透率反而降低。在3类化学刺激剂中,土酸对长石类矿物的溶蚀能力最强,而氢氧化钠溶液对石英的溶蚀能力最强,但氢氧化钠溶液在溶解岩石样品裂隙表面矿物后极易形成非定形态二氧化硅或非定形态铝硅酸盐蚀变矿物并阻塞裂隙,反而对化学刺激效果造成负面影响。总体来看,土酸是青海共和盆地干热岩体的最佳化学刺激剂。在中等注入速度(3 mL·min^-1)条件下,土酸对岩石样品的溶蚀程度就可达到最高;在此基础上进一步降低流速,则可能使溶解组分更易从液相中沉淀而充填于样品裂隙,导致样品渗透率有所下降。  相似文献   

基于UF、GFC及RP-HPLC的长牡蛎(Crassostrea gigas)蛋白抗衰老小分子活性肽(Zel'ner)的纯化及结构解析     

何定芬  谢超  梁佳  梁瑞萍  李海波 《海洋与湖沼》2020,51(1):141-147

牡蛎肉质鲜美,营养丰富,具有很高的食用价值。本研究以舟山长牡蛎(Crassostreagigas)为研究对象,以DPPH自由基清除率为测试指标,通过UF、GFC及RP-HPLC等技术,对牡蛎蛋白酶解液进行分离纯化,获得牡蛎蛋白小分子肽样品,并对其氨基酸组成进行营养性评价。研究结果表明:浓度为30%—100%的硫酸铵处理酶解液的分离效果明显优于低于浓度为30%硫酸铵的分离效果,其DPPH自由基清除率达到52.43%;纯化后得到两种牡蛎蛋白小分子肽分别标记为组分a(Mw1kDa)和组分b(1kDaMw3kDa);组分a中牡蛎蛋白小分子肽分子量分布主要为1995.2Da、1258.9Da、1023.3Da、398.1Da;对牡蛎蛋白小分子肽组分a进行检测,发现其中氨基酸种类及含量丰富,其中必需氨基酸(EAA)含量为18.863%,总氨基酸含量(TAA)为43.3748%,必需氨基酸占总氨基酸43.49%,必需氨基酸与非必需氨基酸(NEAA)的比例为76.95%,风味氨基酸(FAA)含量为18.9147%,占总氨基酸含量的43.61%。综上可见,牡蛎蛋白小分子肽具有极高的营养价值和市场经济效益,此研究为牡蛎蛋白抗衰老小分子活性肽(Zel'ner)的开发提供了新的思路和方向。  相似文献